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I think if the legal injection went exactly as planned, it would be painless. But that gets botched all the time.
Fun fact, this same inmate was spared last November because they couldn't find a vein. He's a prime candidate for lethal injection going wrong. It's part of the reason they wanted to use nitrogen toxicity.
States no longer have access to the drugs used in lethal injection because the suppliers didnt want to be associated with all that. IIRC one state tried their own cocktail of drugs recently and it went horribly wrong.
Not toxicity, but asphyxiation. Nitrogen's harmless, but you need oxygen and will sleep fast if you don't get it.
It goes exactly as planned. It's agony, and the prescribed under dosage of the anesthesia ensures it.