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High school? Chemistry. I took it because I had no interest in biology. Turned out to be interesting, so much so that I took Chem II even though it wasn't required to graduate.
Chem II was the hardest math class in high school. I loved it.
College? Computer Organization. It's about how computers work down at the circuitry level. All the programming was in assembly. Easily the hardest class I took in college.
I don't know why the hard classes were always my favorites.
Chemistry was super fascinating. I looked forward to taking chemistry since I was 9-10 years old. A lot more math than I imagined for sure!