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There are many that are results or accidents from experiments. The Flash got his powers from a lab accident. Iron Man's suit is part of his own research. Cyborg from Teen Titans was an experiment from a father trying to save his son. Elonging Man did "a life research on yogi's elasticity" to create a potion that gave him his powers. Plastic Man was also an "accident" with an unidentified chemical.
Ghost Rider and Spawn made deals with the devil to get powers. Spawn even has an actual limit on how much he can use his hellish powers
These are all great answers. As discussed in another answer to a comment (the one on Poison Ivy and Mr Freeze), I agree that "believable" experiments gone wrong based on actual science provide a source of "believable" super powers.
On the other hand: Ghost Rider and Spawn have really nice origin stories which also place restrictions on what they can do not to make the characters god like.