this post was submitted on 24 Mar 2024
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How hot would it have to be?

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[–] Wwwbdd 13 points 8 months ago* (last edited 8 months ago) (2 children)

Oh no, not the ~~mbappe~~ Mpemba effect effect. I refuse to accept that as a real thing, there is just no way the warm water freezes faster. I've read dozens of articles about it, eventually finding some that confirmed for me it's probably just measuring error or subtle differences that aren't being noticed. But that left me thinking if I had to search so hard for the one article that confirms my gut instinct I shouldn't lean into it too hard

Like you have two cups of identical water, eventually the warm water becomes the cold water. If I then use that previously warm water as my cold water and start the experiment over with another glass of warm water, what now? And don't tell me water has memory.

My favorite explanation is imagine two cars on a track 100 meters long. The far end is the track is hard asphalt and cars can drive fast. The track gets rougher and muddier the closer you are to the finish line, so the first 50 meters are covered in seconds, the next 25 meters are slower, and the final 5 meters the cars are crawling. You start one car at the 100 meter line and one starts at 10 meters. If you're observing this race from the top of a 50 storey building above the track, you'd understandably think "wow, that car that started far away was so much faster! For sure it won" even though in the last few feet it was neck-and-neck.

[–] Brokkr 6 points 8 months ago (1 children)

The reason the hot one freezes first is because the hot one evaporates more, thereby lowering it's mass. The amount of energy that must be removed from water to cool it is small compared to the amount of energy to freeze the water. Therefore, the mass of the water that freezes determines the total energy much more strongly than the starting temperature.

[–] [email protected] 4 points 8 months ago (2 children)

Actually, it doesnt exist.
Previous experiments accounted for evaporation by using sealed containers, and still observed mpemba phenominon.

A recent-ish study managed to control factors for all the proposed reasons of the mpemba phenominon, and found no difference between freezing cold and hot water.
They found the location of the temperature probe to be more of a factor than anything else.
https://youtu.be/SkH2iX0rx8U

Essentially, any observations of this can be accounted for by margins of error.
So in isolation, hot water does not freeze faster than cold water.
Any observation of this are from environmental effects (extra nucleation sites in the water, different freezing conditions etc).
So the laws of thermodynamics still hold.
However, what these environmental factors are and how they contribute arent yet understood.

[–] Brokkr 5 points 8 months ago

Thanks for the video. As it notes, the observations are real, but the explanation may not be known.

However, preventing the evaporation and then finding that the process does not occur kind of proves the evaporation theory, so I'm not sure that point works the way that you or Derek claim it does, unless I'm misunderstanding.

Lastly, I'm not claiming nor do I believe that there is some mystical way of violating the laws of thermo. I'm claiming that when the mass of water is reduced that the total latent heat is also reduced; that is completely consistent with thermo.

[–] Wwwbdd -1 points 8 months ago

That's what I'm talking about! That's for digging that up. It just never passed the smell test for me, I always called bs

[–] CrayonRosary 2 points 8 months ago (1 children)

mbappe effect

You read dozens of articles and aren't even close to spelling his name right?

You just cut his name into a thousand pieces and there's blood everywhere.

[–] Wwwbdd 2 points 8 months ago (1 children)

Ahhh damn! I was about to board a plane and didn't bother googling it, mixed him up with the footballer

[–] bitchkat 1 points 8 months ago

I had a chuckle thinking about the mbappe effect being researched by Hanson, Hanson, and Hanson.