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Nitrogen asphyxiation may not be unpleasant, but being executed certainly causes duress.
If the method of execution takes 8 minutes, and makes you "loopy" during that time, while contemplating your impending death, then that's cruel in my opinion.
In my opinion, if you're going to execute someone then brevity and certainty must surely be required to make it humane.
Imagine them hanging you upside down trying to find a vein for legal injection and being unable to do so for 2 hours. A firing squad would be better in many ways.
Firstly, death causes twitching. And it's not fucking pretty. Most animals, humans included, have a very wide array of stuff that their body does even after they are fully unconscious. It's not at all surprising that bystanders were freaked out, even in ideal circumstances.
You should really look into apoxia. When done right (and I'm not arguing that the execution in the article was done right), it's a minute, maybe two. And that's probably less time than you'd spend on a firing line.
The reality is that there simply is no "perfect" way to kill someone who doesn't want to die. We could give them a choice, possibly, but will they even choose?
Nitrogen asphyxiation, done right, is humane. There is no pain. But one way or the other, the person's gonna know it's happening, no matter the method used to execute them.
Again, none of this is to condone execution as a consequence of crime. I don't think the state is qualified to make the call.