Debian with the Awesome WM. I'm biased because that's what I use.
Linux
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Linux is a family of open source Unix-like operating systems based on the Linux kernel, an operating system kernel first released on September 17, 1991 by Linus Torvalds. Linux is typically packaged in a Linux distribution (or distro for short).
Distributions include the Linux kernel and supporting system software and libraries, many of which are provided by the GNU Project. Many Linux distributions use the word "Linux" in their name, but the Free Software Foundation uses the name GNU/Linux to emphasize the importance of GNU software, causing some controversy.
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DDE?
I like the default look of Nitrux
Logos and soft branding are important for my aesthetic pleasure so I like Fedora GNOME with Papirus icons and Oxygen Blue cursors. Manjaro GNOME, similarly set up, would be my second choice.
Manjaro Sway
I like simple default, so it is easier to customize. But If I have to keep the default I would say Garuda.
Nitrux looks pretty nice
Current distributions, I like EndeavourOS sway edition and Window Maker Live (wmlive).
Historically, I liked HP-UX and OpenSolaris with Gnome and the Nimbus theme. Linux Mint Darnya was nice. So was OpenSUSE 9.3 I think with Gnome and its custom launcher. Red Hat Enterprise Linux / Scientific Linux 6 was nice looking. We went a couple of years without CentOS so everyone used SL6.
It's dead now, but Apricity was the first distro I really enjoyed the look of. Now I know better than to care about out of box appearance.
Out of the box experience is valuable though. No every user wants to tinker for an afternoon to make a system suit their needs. Some want to install and go, nothing wrong with that.
Out of box experience is a personal preference. It always has been. Every person expects something different so I don't really care about it anymore.
Weird way to misspell desktop environment. Or wm defaults. A gnome reskin isn't a distro.
Anything with GNOME is visually appealing but unfortunately the usability is pure garbage. KDE is the exact opposite and Xfce is quick but sits on an awkward place.