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Water chlorination levels in US and EU likely increase cancer risk, study finds
(www.theguardian.com)
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The residue left over after boiling water is probably mostly calcium (if white) or iron (if orange/brown). Both are from dissolved minerals in the water source. If you need to clean anything stained by either, vinegar should dissolve the minerals with minimal effort. I'd avoid vinegar on anything stone (like countertops), as some types of stone will dissolve in the presence of acid.
It's more of a yellow and smells vaguely like urine, but also very acerbic and foul. There's off-yellow crystals at the bottom of the chamber. I'm no expert, just I know I'd rather drink my own urine than drink what's left in that chamber after running a gallon through it. It's revolting and makes me gag to smell it.