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Kamala Harris has cast more tie-breaking votes in the Senate than any VP in history (33)
(ballotpedia.org)
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It does. Joe Biden was VP for a lot longer than Harris, but according to the table linked in the OP, he cast 0 tie-breaking votes; if you look at Senate composition during that time, you can see that there was always a very clear majority for one party. Since 2017 it's always been fairly close to 50-50, so there needed only to be a few (if any) senators breaking from their party to create ties, so Pence and Harris got plenty of opportunities to cast tie-breaking votes.