It looks like the 91% natural ingredients version has benzyl alcohol as a preservative which is typically synthetically derived and in my experience can drastically shift the bio-based ratio.
As far as I can see, the rest of the ingredients are the same, but the sourcing of those ingredients could be different which could also shift the naturally derived percentage.
I haven’t heard that before but I don’t work on hair care products very often. Benzyl alcohol is used as a preservative in lots of cosmetic products though. It can be considered an allergen for some people, but overall it’s pretty safe (as far as we know so far).