I found C# to pretty much be python just with strict types and semicolons. Jumped right into it really on my first job and it worked out pretty fine, granted I got to orient myself in the existing project where I started.
You are perhaps already familiar, but some things stand out like public/private annotations and other class related things like interfaces which work to create a more organized and controlled use compared to pythons "we are all consenting adults" approach were nothing ever really truly blocked from you. It depends a little on what you want to do/use it for, there's frameworks and different uses like WPF / .NET for the frontend.
While it may be too basic for you, ZetCode was useful for me back when learning PyQt in python, so you might find some use with the C# intro: https://zetcode.com/all/#csharp